| Player | Year | Team | Medal | Notes |
| Kuk, Dustin | 1994-95 | USA | ||
| Niittymaki, Antero | 1996-97 | Finland | ||
| Stuart, Mike | 1996-97 | USA | ||
| Groulx, Danny | 1997-98 | Canada-Quebec | Bronze | |
| Helminen, Dwight | 1999-00 | USA | ||
| Maiser, Justin | 1999-00 | USA | ||
| McClement, Jay | 1999-00 | Canada-Ontario | Silver | |
| Plihal, Tomas | 1999-00 | Czech Republic | ||
| Bernier, Steve | 2000-01 | Canada-Quebec | ||
| Bernier, Steve | 2001-02 | Canada-Quebec | ||
| Lawrence, Chris | 2003-04 | Canada-Ontario | Gold | |
| McLaren, Frazer | 2003-04 | Canada-Western | ||
| Setoguchi, Devin | 2003-04 | Canada-Pacific | Silver | |
| Marcou, James | 2004-05 | USA | ||
| McGinn, Jamie | 2004-05 | Canada-Ontario | ||
| Sheppard, James | 2004-05 | Canada-Atlantic | Bronze | |
| Couture, Logan | 2005-06 | Canada-Ontario | ||
| Pelech, Michael | 2005-06 | Canada-Ontario | ||
| Sateri, Harri | 2005-06 | Finland | ||
| Sexsmith, Tyson | 2005-06 | Canada-Pacific | ||
| Doherty, Taylor | 2007-08 | Canada-Ontario | Gold | |
| Tam, Mikael | 2007-08 | Canada-Quebec | ||
| Wrenn, William | 2007-08 | USA | Silver | |
| Abeltshauser, Konrad | 2008-09 | Germany | ||
| Anderson, J.P. | 2008-09 | Canada-Ontario | Gold | |
| Beukeboom, Brock | 2008-09 | Canada-Ontario | Gold | |
| Guimond, Sacha | 2008-09 | Canada-Quebec | ||
| Hamilton, Freddie | 2008-09 | Canada-Ontario | Gold | |
| Goodrow, Barclay | 2009-10 | Canada-Ontario | Silver | |
| Ryan, Joakim | 2009-10 | Sweden | Bronze | |
| Thomson, Ben | 2009-10 | Canada-Ontario | Silver | |
| Hamonic, Justin | 2010-11 | Canada-Western | ||
| Lane, Matt | 2010-11 | USA | Gold | |
| Bergman, Julius | 2011-12 | Sweden | ||
| Hitchcock, Ryan | 2012-13 | USA | Bronze | |
| Salitoro, Dante | 2012-13 | Canada-Ontario | ||
| Quenneville, David | 2014 | Canada-White | Alternate captain | |
| Durandeau, Arnaud | 2015 | Canada-Black | ||
| Skarek, Jakub | 2015 | Czech Republic |
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